Search results for "Spectroscopic analysis"

showing 5 items of 5 documents

Comprehensive Study on the Performance of Waste HDPE and LDPE Modified Asphalt Binders for Construction of Asphalt Pavements Application

2022

This research is aimed at investigating the mechanical behavior of the bitumen by the addition of high-density polyethylene (HDPE) and low-density polyethylene (LDPE) obtained from waste plastic bottles and bags. Polymers (HDPE and LDPE) with percentages of 0%, 2%, 4%, and 6% in shredded form by weight of bitumen were used to evaluate the spectroscopic, structural, morphological, and rheological properties of polymer-modified binders. The rheological properties for different factors; viscosity (ἠ) from Rotational Viscometer (RV), rutting factor G*/Sin (δ), fatigue characteristics G*. Sin (δ), for the modified binder from dynamic shear rheometer (DSR), Short and long-term a…

Polymers and Plasticswaste polyethyleneXRDcreep analysiSEMspectroscopic analysimorphological analysiGeneral Chemistrywaste polyethylene; spectroscopic analysis; morphological analysis; XRD; creep analysis; SEMPolymers
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La pittura vascolare attica a fondo bianco: la prospettiva archeologica, l'apporto dell'indagine scientifica

2017

Il presente contributo intende offrire nuovi spunti di ricerca sui vasi attici a fondo bianco e sulla relativa tecnica pittorica. In particolare, è stato selezionato come caso di studio il cratere del Pittore della Phiale (450-440 a.C.) con il mito di Perseo e Andromeda, esposto nel Museo Archeologico di Agrigento. La prima parte del lavoro si concentra sugli aspetti archeologici e storico-artistici, cercando di ricostruire il ruolo di questa tecnica nella produzione figurativa dell’artigiano e il rapporto tra il cratere di Agrigento e gli altri prodotti del Pittore della Phiale. Inoltre, viene considerata la connessione tra tecnica e con- testo di utilizzo e acquirenti o “committenti”, la…

Tecnica a fondo bianco Agrigento Pittore della Phiale analisi spettroscopiche fluoriescenza a raggi X TR-FTIR.Settore L-ANT/07 - Archeologia ClassicaWhite-ground technique Agrigento Phiale Painter spectroscopic analysis X-ray fluorescence TR-FTIRSettore CHIM/02 - Chimica Fisica
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Lateral Fusion of Chemical Vapor Deposited N = 5 Armchair Graphene Nanoribbons

2017

Bottom-up synthesis of low-bandgap graphene nanoribbons with various widths is of great importance for their applications in electronic and optoelectronic devices. Here we demonstrate a synthesis of N = 5 armchair graphene nanoribbons (5-AGNRs) and their lateral fusion into wider AGNRs, by a chemical vapor deposition method. The efficient formation of 10- and 15- AGNRs is revealed by a combination of different spectroscopic methods, including Raman and UV−visnear-infrared spectroscopy as well as by scanning tunneling microscopy. The degree of fusion and thus the optical and electronic properties of the resulting GNRs can be controlled by the annealing temperature, providing GNR films with o…

Annealing (metallurgy)Nanotechnology02 engineering and technologyChemical vapor deposition010402 general chemistryOptoelectronic devicesSpectroscopic analysisCatalysis; Chemistry (all); Biochemistry; Colloid and Surface Chemistry01 natural sciencesBiochemistryCatalysislaw.inventionsymbols.namesakeColloid and Surface ChemistrylawChemical vapor depositionSpectroscopyScanning tunneling microscopyElectronic propertiesFusionChemistryCommunicationChemistry (all)General Chemistry021001 nanoscience & nanotechnologyVapor deposition0104 chemical sciencesElectronic propertiessymbolsScanning tunneling microscopeGraphene0210 nano-technologyRaman spectroscopyGraphene nanoribbonsJournal of the American Chemical Society
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Interaction of metal ions with N-glycosylamines: isolation and characterization of the products of 4,6-O-benzylidene-N-(o-carboxyphenyl)-β-D-glucopyr…

2001

Metal-ion complexes of Li+, Na+, K+, Mg2+, Ca2+, Ba2+, Pb2+, Cd2+, Hg2+ with 4,6–O–benzylidene–N–(o–carboxyphenyl)–β–D–glucopyranosylamine were synthesized and isolated as solid products and characterized by analytical means as well as by spectral techniques, such as, 1H and 13C NMR, FTIR, absorption, FAB mass spectrometry, optical rotation and CD. While the alkali metal ions formed ML type of complexes, the other metal ions formed ML2 type complexes. Molecular weights of the complexes of Li+, Na+ and K+ were established based on the molecular-ion peaks in the FAB mass spectra. The saccharide portion remians in the β-anomeric form even after the complexation. The spectral data, as well as t…

GlycosylationMagnetic Resonance SpectroscopyMetal ions in aqueous solutionInorganic chemistrySpectroscopic AnalysisMass spectrometryBiochemistryAlkali MetalsMass SpectrometryAnalytical ChemistryMetals Alkaline EarthSpectroscopy Fourier Transform InfraredQualitative inorganic analysisIonsGlucosamineChemistryFourier Transform Infrared SpectroscopyCircular DichroismOrganic ChemistryGeneral MedicineMercuryCarbon-13 NMRAlkali metalMolecular WeightCrystallographyLeadModels ChemicalMetalsMass spectrumAmine gas treatingAbsorption (chemistry)CadmiumIndraStra Global
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Synthesis, spectroscopic, and X-ray structural study of aqua-bis(thymine-N 1 ,N 4 )-ethylenediamine copper(II)dihydrate [Cu(Thy) 2 (en)(H 2 O)].2H 2 O

2016

International audience; A new compound of thyminato anions and ethylenediamine with five-coordinate Cu(II) is synthesized. Elemental analysis and spectroscopic techniques (IR, UV-visible) were used to characterize this compound and its crystal structure was determined by single-crystal X-ray diffraction. The crystal structure consists of the neutral mononuclear complex [Cu(Thy)(2)(en)(H2O)]center dot 2H(2)O. The environment around Cu(II) ion exhibits a square pyramidal geometry with two nitrogen atoms of ethylenediamine and two other nitrogen atoms of the monodentate monoanions of thymine building the equatorial plane. The oxygen atom from H2O molecule occupies the apical position. The comp…

DenticityInorganic chemistrychemistry.chemical_elementEthylenediamineCrystal structure[CHIM.INOR]Chemical Sciences/Inorganic chemistry010402 general chemistry010403 inorganic & nuclear chemistry01 natural sciencesIonInorganic Chemistrychemistry.chemical_compoundMoleculeuracilbasePhysical and Theoretical Chemistrycomplexescrystal copper(II) complexspectroscopic analysisbinding-sites[ CHIM.INOR ] Chemical Sciences/Inorganic chemistryCopperSquare pyramidal molecular geometry0104 chemical sciencesThymineCrystallographychemistrynickel(ii)ethylenediamineThyminecrystal-structures
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